Tetrahydropentalenyl-phosphazene constrained geometry complexes of rare-earth metal alkyls
نویسندگان
چکیده
منابع مشابه
Tetrahydropentalenyl-phosphazene constrained geometry complexes of rare-earth metal alkyls.
Reactions of Cp™HPPh2 (1, diphenyl(4,4,6,6-tetramethyl-1,4,5,6-tetrahydropentalen-2-yl)phosphane) with the organic azides AdN3 and DipN3 (Ad = 1-adamantyl; Dip = 2,6-di-iso-propylphenyl) led to the formation of two novel CpPN ligands: P-amino-cyclopentadienylidene-phosphorane (Cp™PPh2NHAd; L(Ad)H) and P-cyclopentadienyl-iminophosphorane (Cp™HPPh2NDip; L(Dip)H). Both were characterized by NMR sp...
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ژورنال
عنوان ژورنال: Dalton Trans.
سال: 2014
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c3dt53596g